By J.D. Burton, P.G. Brewer, R. Chesselet

The. complex examine Inst i tute (ARI) on Dynamic procedures within the Chemistry of the higher OCean had its origins in discussions by means of the NATO targeted Programme Panel on Marine Sciences in the course of 1978 whilst a variety of themes for destiny ARIs was once being thought of. What was once then envisaged used to be a workshop on chemical facets of the oceanic combined layer, at which think of­ ation will be given to the inputs, biking and elimination of fabric, and the issues considering the quantitative overview of fluxes. It used to be realised that any try and version chemical tactics would want the energetic collaboration of employees from different fields, in particular actual oceano­ graphers interested by air-sea interplay and turbulence, and organic oceano~raphers with services in basic productiveness and the biking of particulate and dissolved natural fabric. As plans for the ARI constructed additional a a bit varied emphasis emerged, curious about the query as to how chemists may still set approximately gazing an atmosphere as variable and dynamic because the higher ocean and choosing the precise scales for the framework of measurements to check a selected technique, in particular within the gentle of present wisdom of actual methods of shipping and combining. It was once undeniable that the capabil­ ity of actual oceanographic easy methods to get to the bottom of alterations on small spatial and temporal scales is significantly prior to the features of biologists and chemists who depend upon discrete sampling and intricate lab­ oratory manipulations so as to receive such a lot in their data.

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20 ~ 40 ~ c::l 60 ....... 5 . " "," " \. r::: r· " ~ \/, ....... : Fig. 3. Chlorophyll variability on a Batfish transect in the Gulf of Maine, plotted against depth and sigma-t. 5 km. 0 mg m- 3 chlorophyll contour within a vertical gradient decreasing with depth (after Denman and Mackas, 1978). 34 processes are to be understood for, say, metals such as cadmium, copper or zinc, then the dynamics in the upper layer will need to be investigated in the same detail given to the physics and to certain parts of the biology.

35 Apr. 25 Apr. 27 Apr. 29 May 2 May 4 May 5 May 8 May 10 May 14 CELL DIAMETER, pm Fig. 4. Particle size distribution at 10 m depth on the Fladen Ground, North Sea, in 1976 (from Gamble, 1978) . 0 100 A '"~ "E:: 40 80 KM 50 SHETLAND NORWAY Fig. 5. (A) Plankton volumes and (8) stage distribution of the dominant copepod Cal anus finmarchicus along a transect across the northern North Sea (from Geophysical Institute, Bergen, 1976). 36 Data on fast flux rates, from sediment traps and from other sources, make this less acceptable.

Garrett screens have proved the most popular of the microlayer samplers so far invented. other devices, collecting similar thicknesses and volumes, Which have been found useful include a rotating ceramic drum (Harvey, 1966) and a glass plate (Harvey and Burzell, 1972). Since they can harvest reasonably large volumes, sophisticated chemical analysis of the water is poSSible, and these "micro layer" samplers have so far been the mainstay of research into the chemical composition of near-surface seawater.

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