By Dr. Surendra K. Saxena, Dr. Nilanjan Chatterjee, Dr. Yingwei Fei, Dr. Guoyin Shen (auth.)

Over the past thirty years profound advancements in expe- rimental thoughts to degree extreme temperature and pressu- res and thermodynamic homes of minerals have happened. This technical improvement has been matched by means of an elevated sophistication in using theoretical how to receive new information or increase the standard of current information. utilizing those newtechniques, Assessed Thermodynamic facts on Oxides and Silicates represents the winning test of the authors to advance an internally systematized info base which satis- fies the restrictions of calorimetric measurements, part equilibrium info, measured thermophysical houses of a section, and warmth capacities and entropies predicted from lat- tice vibrational versions.

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Extra resources for Thermodynamic Data on Oxides and Silicates: An Assessed Data Set Based on Thermochemistry and High Pressure Phase Equilibrium

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They both suggest a relatively ideal behavior of the orthopyroxene and garnet solutions. 4) Enthalpy and entropy of almandine are available from calorimetric experiments of Chatillon-Colinet et al. 6 kJ/mol of cation, an average of two different methods) and Metz et al. K of cation). 5). k). The heat capacity expression for hercynite used by Saxena and Eriksson (1983b) is adjusted here. The entropy is from Robie et al. (1978). Enthalpy is adjusted within the error limits of Robie et al. 5 KJ/mol).

The heat capacity is assumed to be the same as that of enstatite. Diopside The properties listed in Robie et al. (1978) are adopted. These data are from calorimetric sources. Hedenbergite The values are as recommended by Saxena et al. (1986). All values in their study were adjusted from the recommended values of Helgeson et al. (1978) to fit the equilibrium data on quadrilateral pyroxenes from Lindsley (1983). Recently, Haselton et al. (1987) determined the heat capacity of hedenbergite by lowtemperature.

Also, the solution parameters show a closely symmetric, not very non-ideal solution. Since Perchuk and Lavrent'eva's data cover a wide range of the binary and the results obtained are much better, the 46 Assessment of Data on Some low Pressure Phases free-energy of annite and the interaction parameters of the phlogopite-annite solution obtained from their data are recommended for use in calculations. An uncertainty of 700 joules is found in the enthalpy of annite. 5 J/mol The molar volume of annite is from Robie and Bethke (1963).

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