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In fact, the problem of describing charge transfer is a classical percolation problem, modified by quantum effects. e. varistors). We propose to use a similar model in the present work to relate the exchange current densities of the cathodic reactions to the distribution of SPPs in the barrier layer, and hence ultimately to the heat treatment of the alloy. The importance of accurately modeling the cathodic processes results from the fact that they, to a large extent, control the corrosion potential, which in turn controls the thickness of the barrier oxide layer.