By Didier Astruc

From the very outset, arene chemistry has been some of the most various and intensively studied parts of analysis, and has witnessed a quick development during the last few years particularly. This publication, edited through the popular chemist Didier Astruc, illustrates the wonderful range to be present in this attention-grabbing box. * 16 contributions from authors who learn like a "Who's Who" of arene chemistry: D. Astruc, U. H. F. Bunz, A. de Meijere, F. Diederich, okay. H. D?tz, ok. S. Feldman, W. D. Harman, J. F. Hartwig, H. Hopf, J. ok. Kochi, S. Quideau, F. Rose-Munch, L. T. Scott, V. Snieckus, J. F. Stoddart, and A. Suzuki * the publication covers all of the vital features from background to the newest advancements, together with supramolecular chemistry, coupling reactions, cyclophanes, transition-metal arene complexes, and arene functionalization between many others. * crucial analyzing for each natural or bioorganic chemist and people operating with organometallics, catalysis, and fabrics.

Show description

Read or Download Modern Arene Chemistry: Concepts, Synthesis, and Applications PDF

Best chemistry books

Water Scarcity in the Mediterranean: Perspectives Under Global Change

Water shortage impacts hydrologic assets, structures connectivity, biodiversity, water caliber, and river surroundings functioning. It has direct affects on fiscal sectors that use and rely on water, reminiscent of agriculture, tourism, undefined, strength and shipping. The Mediterranean Basin is without doubt one of the areas on the earth so much at risk of weather adjustments, in addition to the most impacted via human water call for.

Additional info for Modern Arene Chemistry: Concepts, Synthesis, and Applications

Example text

Williams, J. Chem. , Chem. Commun. 1967, 719–720. K. Jacob, M. Sigalov, J. Y. Becker, A. Ellern, V. Khodorkovsky, Eur. J. Org. Chem. 2000, 2047–2055. J. Tatsugi, M. Okumura, Bull. Chem. Soc. Jpn. 1978, 51, 1227–1228. S. D. Mekhtiev, M. R. Musaev, A. G. Gasanov, Azerb. Khim. Zh. 1971, 93–97. Homodesmic reaction: 7 þ 1ÁHþ ! 7ÁHþ þ 1 (DHcalc ¼ À13:5 kcal molÀ1 ). Calculation performed at the pBP/DN**//AM1 level of theory using the Spartan collection of programs [31]. 31 32 2 Oligounsaturated Five-Membered Carbocycles – Aromatic and Antiaromatic Compounds in the Same Family Rainer Haag and Armin de Meijere Abstract Most compounds containing oligounsaturated five-membered carbocycles ranging from cyclopentadiene to C20 fullerene display interesting electronic and structural properties.

Obviously, any factor that favors the second of these two reactions (dimer ! trimer) over the first (monomer ! dimer) will set the stage for a cyclization and dehydration to the desired tris-annulated benzene. Conversely, if the first aldol step is fast relative to the second one, all of the monomer will be converted to the dimer, but there will then be no more monomer left to serve as the nucleophilic partner for the second aldol step, and the reaction will terminate at the acyclic dimer stage. , 7ÁHþ/7 vs.

Lawton, J. Am. Chem. Soc. 1966, 88, 380. K. Yamamoto, T. Harada, N. Masao, J. Am. Chem. Soc. 1983, 105, 7171. H. A. Staab, F. N. Diederich, Angew. Chem. Int. Ed. Engl. 1978, 17, 372. E. Clar, Polyaromatic Hydrocarbons, Academic Press, London, 1964. : I. Gutman), Topics in Current Chemistry, Springer, Heidelberg, 1992, vol. 162. Y. Stritana-Anant, T. J. Seiders, J. S. : A. de Meijere), Springer, Heidelberg, 1998, 196, 1. First report of a three-fold symmetric phenylene: K. P. C. Vollhardt, J. Am.

Download PDF sample

Download Modern Arene Chemistry: Concepts, Synthesis, and by Didier Astruc PDF
Rated 4.30 of 5 – based on 20 votes