By H. J. Kandiner (auth.)
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97) ermittelten Werte der Suszeptibilität von Ir3 + (Messungen an handelsüblichem IrCl 3) für 20° unter der Annahme der Gültigkeit des CuRIEsehen Gesetzes (s. jedoch S. 32) berechnet und als "effektive Magnetonenzahl" bezeichnet, E. C. STONER (Magnetism and Matter, London 1934, S. 282, 339). oo theoret. Wert, unter der Annahme berechnet, daß in IrCl 3 homöopolare Bindungen vor-· liegen, D. M. BosE, H. G. BHAR (Z. Phys. 48 [I928] 720). 4 aus Suszeptibilitätsmessungen an handelsüblichem 2 IrCl3 • 3 H 2 0 bei Zimmertemp.
N. BoHR (Phil. , [6) 26 [I9I3] 497), W. KossEL (Ann. Phys. [4] 49 [I9I6] 229, 255, 352), R. LADENBURG (Z. Elektroch. 26 [I920) 264), C. R. BuRY (J. Am. Soc. 43 [I92I] I6o7, I6o8). ldzustand folgende Elektronenverteilung: in den Schalen K bis Mv dieselbe Verteilung wie für die Elemente der vorhergehenden Periode (s. z. B. -Nr. 64, S. 9); in den weiteren Schalen: Schalenbezeichnung Nr Nu Nm Nrv Nv Nvr. 8 2 2 2 4 7 '--v--_ ____, '--~ Termsymbole • . 4s1 4P 8 4d10 4f1' ss• SP' sd7 6s1 E. C. STONER (Phil.
Hierzu J. C. McLENNAN, A. B. McLAY, H. G. SMITII (Pr. Roy. Soc. A 112 [1926] 78), M. N. SAHA, B. B. RAY (Phys. Z. 28 [1927] 22I), M. N. SAIIA (Phys. Z. 28 [1927] 469), R. N. Gnosn (Quart. J. Indian chem. Soc. 4 [1927] 423) -ergibt sich nach quantenmechan. Überlegungen von W. PAULI (Z. Phys. 31 [192s] 76s), W. HElSENBERG (Z. Phys. 32 [1925] 84I), F. HuND (Z. Phys. 33 [I925)'345) bei vollständiger Besetzung die Beziehung z = 2(2! +I), worin I= k - I die Nebenquantenzahl ist. Wenn ferner den I-Werten o, 1, 2, 3 die Termsymbole s, p, d, f zugeordnet werden, dann folgt die in der letzten Zeile der obigen Tabelle angegebene symbol.