By Nikos Tagmatarchis, Maurizio Prato (auth.), Kosmas Prassides (eds.)
N. Tagmatarchis, M. Prato: Organofullerene Materials.- S. Saito, ok. Umemoto, T. Miyake: digital constitution and Energetics of Fullerites, Fullerides, and Fullerene Polymers.- M. Takata, E. Nishibori, M. Sakata, H. Shinohara: cost Density point buildings of Endohedral Metallofullerenes by way of MEM/Rietveld Method.- B. Sundqvist: Polymeric Fullerene levels shaped below Pressure.- S. Margadonna, Y. Iwasa, T. Takenobu, okay. Prassides: Structural and digital houses of chosen Fulleride Salts.- V. Brouet, H. Alloul, S. G� r� j, L. Forrò: NMR experiences of Insulating, steel, and Superconducting Fullerides: significance of Correlations and Jahn-Teller Distortions.- M.S. Golden, T. Pichler, P. Rudolf: cost move and Bonding in Endohedral Fullerenes from excessive power Spectroscopy.- D. Arcon, R. Blinc: Jahn Teller impact and Fullerene Ferromagnets.
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Extra resources for Fullerene-Based Materials: Structures and Properties
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56 © Springer-Verlag Berlin Heidelberg 2004 42 S. Saito et al. Abbreviations DFT LDA TB fcc bcc bco sc Density functional theory Local density approximation Tight-binding Face-centered cubic Body-centered cubic Body-centered orthorhombic Simple cubic 1 Introduction In the last two decades, atomic clusters have attracted great interest first in physics and chemistry, and later in materials science and engineering. Accordingly, their physical and chemical properties are often distinct from those of the bulk phase [1].
In addition, by a modification of the Bingel cyclopropanation reaction, a product containing ten malonate groups was prepared, providing Gd@C60 [C(COONa)2]10 [301]. The synthesized material was found to be as effective as the commercially available gadolinium chelate MRI agents. Finally, a new functionalized gadolinium endohedral metallofullerene was announced. Utilizing the same type of reaction for the modification of Sc3N@C80, namely Diels–Alder [4+2] cycloaddition of 6,7-dimethoxyisochroman-3-one, the corresponding trimetallic nitride endohedral metallofullerene derivative, Gd2ScN@C80, was synthesized with the perspective to be water soluble once the methoxy groups of the isochromanone moiety are replaced with carboxylic ones [302].
Tomberli V, Da Ros T, Bosi S, Prato M (2000) Carbon 38:1551 287. Bosi S, Da Ros T, Castellano S, Banfi E, Prato M (2000) Bioorg Med Chem Lett 10:1043 288. Kordatos K, Da Ros T, Bosi S, Vazquez E, Bergamin M, Cusan C, Pellarini F, Tomberli V, Baiti B, Pantarotto D, Georgakilas V, Spalluto G, Prato M (2001) J Org Chem 66:4915 289. Brettreich M, Hirsch A (1998) Tetrahedron Lett 39:2731 290. Maggini M, Scorrano G, Bianco A, Toniolo C, Sijbesma RP,Wudl F, Prato M (1994) J Chem Soc Chem Commun 305 291.