By Anthony W. Czarnik
content material: Supramolecular chemistry, fluorescence, and sensing / Anthony W. Czarnik --
Synthesis and learn of crown ethers with alkali-metal-enhanced fluorescence : quest for flashy crowns / L.R. Sousa, B. Son, T.E. Trehearne, R.W. Stevenson, S.J. Ganion, B.E. Beeson, S. Barnell, T.E. Mabry, M. Yao, C. Chakrabarty, P.L. Bock, C.C. Yoder, and S. Pope --
Ion reputation detected through alterations in photoinduced cost or power move / Bernard Valeur, Jean Bourson, and Jacques Pouget --
Fluorescent photoinduced electron-transfer sensors : the straightforward common sense and its extensions / Richard A. Bissell, A. Prasanna de Silva, H.Q. Nimal Gunaratne, P.L. Mark Lynch, Colin P. McCoy, Glenn E.M. Maguire, and K.R.A. Samankumara Sandanayake --
Tunable fluorescence of a few macrocyclic anthracenophanes / H. Bouas-Laurent, J-P. Desvergne, F. Fages, and P. Marsau --
Fluorescent cyclodextrins for detecting natural compounds with molecular attractiveness / Akihiko Ueno --
Intrinsic chromophores and fluorophores in artificial molecular receptors / Thomas W. Bell, Daniel L. Beckles, Peter J. Cragg, Jia Liu, James Maioriello, Andrew T. Papoulis, and Vincent J. Santora --
Fluorescent sign transduction in molecular sensors and dosimeters / Anthony W. Czarnik --
Fluorescent and photochemical probes of dynamic biochemical indications inside of dwelling cells / Roger Y. Tsien --
1,2-Bis(2-aminophenoxy)ethane-N, N, N', N', -tetraacetic acid conjugates used to degree intracellular Ca² focus / Michael A. Kuhn --
Fluorescent chemosensors for tracking potassium in blood and throughout organic membranes / Divakar Masilamani and Mariann E. Lucas --
Fluorescent probes in stories of proteases / furnish A. Krafft and Gary T. Wang --
Lifetime-based sensing utilizing phase-modulation fluorometry / H. Szmacinski and J.R. Lakowicz.
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Additional resources for Fluorescent Chemosensors for Ion and Molecule Recognition
Example text
Variation in transfer efficiency as a function of the donor-acceptor distance. The arrows indicate favorable average distances before and after complexation for the tuning of transfer efficiency in a broad range. (Reproduced with permission from ref. 23. Copyright 1992 American Chemical Society). ; ACS Symposium Series; American Chemical Society: Washington, DC, 1993. ch003 Literature cited 1. Löhr, H. ; Vögtle, F. Acc. Chem. Res. 1985, 18, 65. 2. ; Ueno, K. Chem. Lett. 1982, 1853. 3. Talanta, 1984, 31, 749.
11. ; Valeur, B. New J. Chem. 1990, 14, 617. 12. ; Desvergne, J. ; Lehn, J. ; Konopelski, J. ; Barrans, Y. J. Am. Chem. Soc. 1989, 111, 8672. 13. Desvergne, J. ; Marsau, P. Pure Appl. Chem. 1992, 64, 1231. 14. ; Borrel, M . ; Valeur, B. Anal. Chim. Acta 1992, 257, 189. 15. ; Valeur, B. J. Phys. Chem. 1993, 97, 4552. 16. ; Le Bris, M . ; Mialocq, J. ; Valeur, B. J. Phys. , 1992, 96, 701. 17. Pacey, G. ; Wu, Y. P. Talanta 1984, 31, 165. 18. ; Mialocq, J. C. Opt. Commun. 1987,64, 264. 19. ; Majenz, W.
Ch003 700 750 36 FLUORESCENT CHEMOSENSORS FOR ION AND MOLECULE RECOGNITION be such that the two carbonyls are on the same side; the resulting close distance between the two coumarin moieties (and possibly stacking) accounts for quenching. The existence of such a folded conformation is supported by the absorption spectra of the complexes with N a , C a and M g which exhibit shoulders on the red edge side arising from ground-state interactions (Figure 5). In contrast, no shoulder is observed in the absorption spectra of the complexes with B a and K because of the absence of ground-state interactions in the extended conformations.