By Matthias Reihmann, Helmut Ritter (auth.), Shiro Kobayashi, Helmut Ritter, David Kaplan (eds.)
"The final twenty years have noticeable an emergence within the use of enzymes as catalysts for polymer synthesis. because of the designated artificial equipment of biocatalysts, new polymers were built and "old" polymers were generated utilizing novel man made ideas. This publication includes seven chapters that disguise in nice deatail using enzymes to synthesize more than a few polymers. It additionally uses a great number of examples to summarize the salient gains of the enzymatic reactions and ensuing polymeric houses. therefore, this e-book could be of curiosity to either professional and nonexpert readers."
from: J. Am. Chem. Soc. 2006, 128, 10633
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Ritter system, and polymers were also prepared from 4-hydroxyphenyl-N-maleimide (57) [48]. All three monomers were polymerized in the form of their cyclodextrin complexes in aqueous buffer solution only. The resulting phenol polymers having the unaffected double bonds in the side chain acted as macromonomers, which could be copolymerized subsequently with MMA or styrene (Scheme 12) [48]. Even polymers containing the reactive vinylcyclopropane group have been successfully polymerized in aqueous medium using the cyclodextrin technique.