By Stefano Bianco (ed.)
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Extra info for CARBON NANOTUBES - FROM RESEARCH TO APPLICATIONS
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2004). Adsorption properties of hydrogen on (10,0) single-walled carbon nanotube through density functional theory. 11, (May 2004) pp. T. E. (2000). Quantized phonon spectrum of single-wall carbon nanotubes. 5485, (September 2000), pp. ; Wu, Y. & Zhang, Z. (2011). High reactivity of metal-free nitrogendoped carbon nanotube for the C-H activation. 4-6, (February 2011), pp. S. & Jeong, S. (2004). 23 (December 2004), pp. 233411-1-233411-4. I. S. (2009). Hydrogen adsorption on nitrogen-doped carbon xerogels.
The broken lines indicate the expected C60-doped amount corresponding to perfect filling of the interstitial nanospaces with C60 in the model structure of C60-pillared SWCNT bundles with hexagonal symmetry. Figure 5 shows the N2 adsorption isotherms of C60-pillared SWCNT bundles. The N2 adsorption amount was dramatically changed by C60-pillaring treatment. 646) is the greatest. 1; the marked low pressure adsorption is more evidently observed in the isotherms of which abscissa is expressed by the log P/P0.
5 µB/atom, depending on their local environments. 4. Dioxygen adsorption on one nitrogen open edge doped CNT(10, 0) The first-principles DFT calculations to study dioxygen O2 adsorption and reduction on the nitrogen edge-doped carbon nanotubes were performed. The calculated results show that the O2 can chemisorbed on a site close to the nitrogen-carbon complex with a tilted slant away from the nitrogen atom and more close to a carbon atom (Fig. 2a and b, Pauling adsorption model). 22 Å in free gas O2 molecule state, see Table 1.