By Robert J Ferrier; Royal Society of Chemistry
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Additional info for Carbohydrate chemistry : monosaccharides, disaccharides, and specific oligosaccharides, A review of the literature published in 1992
90 CH20R CH20R CHzOR \ BnO RO BnO OR OBn OBn 40 Further work has been published on the use of the oxyanion derived from 2,3,4,6tetra-benzyl-D-glucose which is now shown to be effective as a nucleophile in displacing triflate esters from secondary positions of carbohydrates. 93 Otherwise they may be obtained from 1 pivaloates. For example, compound 45, produced in 63% yield by direct pivaloylation of glucose, is cleavable at the Carbohydrate Chemistry 28 anomeric centre by use of hydrazine and acetic acid.
Khim. Zh. (Russ. ), 1991,57,358 (Chem. , 1992,117,234 365). A. A. lsmail, . I Carbohydr. , 1992, 11, 149. B. Adams and L. Lerner, J. Am. Chem. , 1992, 114,4827. T. Tanase, T. Takei, M. Hidai and S . Yano, J. Chem. , 1992, ( S ) 252; (M) 1922. R. Yanagihara, S. Osanai and S . Yoshikawa, Chem. , 1992,89. A. Berger, A. de Raadt. G. Gradnig, M. Grasser, H. L6w and A E . 33,7125. H . Pelmore, G. R. Symons, J. Chem. ,Perkin Trans, 2 , 1992, 149. J. M. Felin, A. Aldaz, J. Clavilier and A. Rodes, J. Electroanal.
J. Mol. Evol.. 1992,35,1 (Chem. Abstr. 1992,117,126 823). K. Walrao. M Nango and K. Tsuda, J. Polym. , Part A: Polym. Chem.. 1992. 30, 2247 (Chem. , 1992,117, 151 580). A. Moromv. React. Kinet. Cad. 71 (Chem. 174 545). Froma, C. Fuganti, A. Mele, G. PedrOcchi-Fanto~and S. Servi J. Org. 57,999. J. Inanaga. Y. Yokoyama and T. 8109. A. piarulli. Poli, C. Scolastico and R. ViUa, Bull. SOC. Chem. Abstr.. 1991,114,229 241). B. Lacourt-Gadras,M. Grignon-Dubois and B. Rezzonico, Curbohydr. Res.. 1992,235,281.
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